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Class 12 Chemistry — questions with answers and worked explanations.
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Class 12 Chemistry
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These questions are drawn from the Pariksha Sutra question bank for Solutions,
part of the Class 12 Chemistry syllabus. Each one shows the correct answer and,
where a method helps, the working behind it.
Read the question, decide your answer before looking, then check the explanation — that is what turns practice
into marks. If a question catches you out, the explanation is the part worth re-reading.
Questions
Question 1
Which of the following is an example of a solid solution in which both the solute and solvent are solids?
- Brass (Cu and Zn alloy)
- Camphor in nitrogen gas
- Amalgam of mercury with sodium
- Aerated water (CO2 in water)
Answer: Brass (Cu and Zn alloy)
Question 2
Calculate the mass percent of urea in a solution made by dissolving 10 g of urea in 90 g of water.
- 90%
- 11.1%
- 10%
- 9%
Question 3
Raoult's law states that the partial vapour pressure of a component in a solution is proportional to its:
- Mole fraction in solution
- Volume in solution
- Mass percent in solution
- Molarity in solution
Answer: Mole fraction in solution
Question 4
A mixture of acetone and chloroform shows negative deviation because:
- A-B interactions are weaker than pure components
- The mixing is highly endothermic
- Both are non-polar liquids
- Hydrogen bonding forms between chloroform H and acetone O
Answer: Hydrogen bonding forms between chloroform H and acetone O
Question 5
18 g of glucose (molar mass 180 g/mol) is dissolved in 1 kg of water (Kb = 0.52 K kg/mol). The elevation in boiling point is:
- 0.52 K
- 0.1 K
- 0.26 K
- 0.052 K
Question 6
A sample of water contains 20 mg of dissolved salt in 1 kg of water. What is the concentration in ppm?
- 200 ppm
- 2 ppm
- 20 ppm
- 0.2 ppm
Question 7
If the partial pressure of a gas over a solution is 2 bar and its Henry's law constant is 50 bar (mole fraction units), the mole fraction of the gas in solution is:
- 0.02
- 0.4
- 0.25
- 0.04
Question 8
Which of the following pairs behaves most nearly as an ideal solution?
- n-hexane and n-heptane
- Water and nitric acid
- HCl and water
- Acetone and chloroform
Answer: n-hexane and n-heptane
Question 9
For a solution with molality 0.5 mol/kg and Kb = 0.52 K kg/mol, the elevation in boiling point is:
- 1.04 K
- 0.13 K
- 0.26 K
- 0.52 K
Question 10
Two solutions having the same osmotic pressure at a given temperature are said to be:
- Isotonic
- Saturated
- Hypertonic
- Hypotonic
Question 11
A solution of oxygen dissolved in nitrogen gas is an example of which type of solution?
- Liquid in gas
- Gas in liquid
- Gas in gas
- Gas in solid
Question 12
How many grams of glucose (molar mass 180 g/mol) are required to prepare 2 L of a 0.5 mol/L solution?
- 360 g
- 90 g
- 45 g
- 180 g
Question 13
For a solution of two volatile liquids A and B, the total vapour pressure is given by:
- pA0 xA + pB0 xB
- pA0 xA - pB0 xB
- pA0 + pB0
- pA0 xB + pB0 xA
Question 14
A maximum boiling azeotrope is formed at a specific composition by solutions showing:
- Negative deviation from Raoult's law
- Zero vapour pressure
- Ideal behaviour
- Positive deviation from Raoult's law
Answer: Negative deviation from Raoult's law
Question 15
Molal elevation constant Kb is also known as the:
- van't Hoff constant
- Cryoscopic constant
- Ebullioscopic constant
- Osmotic constant
Answer: Ebullioscopic constant
Question 16
Which of the following represents a solution of a solid solute in a liquid solvent?
- Sugar dissolved in water
- Ethanol dissolved in water
- Oxygen dissolved in water
- Chloroform mixed with nitrogen gas
Answer: Sugar dissolved in water
Question 17
Which of the following expresses concentration as moles of solute per kilogram of solvent?
- Mass percent
- Molality
- Mole fraction
- Molarity
Question 18
At 300 K, pure liquid A has vapour pressure 100 mm Hg and pure B has 60 mm Hg. If mole fractions are xA = 0.5 and xB = 0.5, the total vapour pressure of the ideal solution is:
- 80 mm Hg
- 160 mm Hg
- 60 mm Hg
- 100 mm Hg
Question 19
Which of the following is NOT a colligative property?
- Depression of freezing point
- Osmotic pressure
- Elevation of boiling point
- Optical activity
Question 20
The molal depression constant (Kf) is also called the:
- Osmotic constant
- Henry's constant
- Cryoscopic constant
- Ebullioscopic constant
Answer: Cryoscopic constant
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